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Olav M Aagaard -

City: Geleen
State/Country: NL
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Olav M Aagaard ( Geleen, NL )
DSM N.V. - Heerlen NL


Olav M Aagaard ( Geleen, NL )
The invention relates to a composite material and a process for manufacturing the composite material by applying at least a single organic barrier layer to a substrate to reduce the oxygen permeability of the substrate. Depending on the intended application, the composite material may also include an outer cover layer over the barrier layer to improve moisture resistance. The preferred materials are triazines, particularly melamine, that are vapor-deposited onto the substrate to form a thin, durable transparent barrier layer.
The invention relates to a composite material and a process for manufacturing the composite material by applying at least a single organic barrier layer to a substrate to reduce the oxygen permeability of the substrate. Depending on the intended application, the composite material may also include an outer cover layer over the barrier layer to improve moisture resistance. The preferred materials are triazines, particularly melamine, that are vapor-deposited onto the substrate to form a thin, durable transparent barrier layer.
The invention relates to a process for the hydrogenation of a polymer composed of diene monomer units and nitrile group containing monomer units in which crosslinks formed as a result of the hydrogenation are broken by adding, before, during or after the hydrogenation, a compound that satisfies the formula R.sub.1 --N(H)--X (I) or (R.sub.1)(R.sub.2)C.dbd.N--Y (II), where R.sub.1 is a hydrogen atom, an alkyl or cycloalkyl group with 1-30 carbon atoms, or an aromatic group with 6-30 carbon atoms and R.sub.2 is an alkyl or cycloalkyl group with 1-30 carbon atoms, or an aromatic group with 6-30 carbon atoms, X is chosen from the group comprising --R.sub.3, --OR.sub.4, --SR.sub.4, --NR.sub.5 R.sub.6, where R.sub.3, R.sub.4 and R.sub.5 are a hydrogen atom, an alkyl or cycloalkyl group with 1-30 carbon atoms or an aromatic group with 6-30 carbon atoms and R.sub.6 is an alkyl or cycloalkyl group with 1-30 carbon atoms or an aromatic group with 6-30 carbon atoms Y is chosen from the group comprising --R.sub.7, --OR.sub.8, --SR.sub.8, --NR.sub.9 R.sub.10 and --N.dbd.CR.sub.11 R.sub.12, where R.sub.7, R.sub.8, R.sub.9, R.sub.10, R.sub.11 and R.sub.12 are a hydrogen atom, an alkyl or cycloalkyl group with 1-30 carbon atoms or an aromatic group with 6-30 carbon atoms, and where it is possible for R.sub.3 -R.sub.12 to also contain one or more heteroatoms from the groups 13, 14, 15, 16 or 17 of the Periodic System of the Elements.