Register or Login To Download This Patent As A PDF
| United States Patent Application |
20080227247
|
| Kind Code
|
A1
|
|
Engel; Brett H.
;   et al.
|
September 18, 2008
|
BARRIER DIELECTRIC STACK FOR SEAM PROTECTION
Abstract
The present invention provides a semiconducting device including a gate
dielectric atop a semiconducting substrate, the semiconducting substrate
containing source and drain regions adjacent the gate dielectric; a gate
conductor atop the gate dielectric; a conformal dielectric passivation
stack positioned on at least the gate conductor sidewalls, the conformal
dielectric passivation stack comprising a plurality of conformal
dielectric layers, wherein no electrical path extends entirely through
the stack; and a contact to the source and drain regions, wherein the
discontinuous seam through the conformal dielectric passivation stack
substantially eliminates shorting between the contact and the gate
conductor. The present invention also provides a method for forming the
above-described semiconducting device.
| Inventors: |
Engel; Brett H.; (Hopewell Junction, NY)
; Lucarini; Stephen M.; (Pleasant Valley, NY)
; Sylvestri; John D.; (Poughkeepsie, NY)
; Wang; Yun-Yu; (Poughquag, NY)
|
| Correspondence Address:
|
SCULLY, SCOTT, MURPHY & PRESSER, P.C.
400 GARDEN CITY PLAZA, Suite 300
GARDEN CITY
NY
11530
US
|
| Assignee: |
INTERNATIONAL BUSINESS MACHINES CORPORATION
Armonk
NY
|
| Serial No.:
|
129117 |
| Series Code:
|
12
|
| Filed:
|
May 29, 2008 |
| Current U.S. Class: |
438/197; 257/E21.266; 257/E21.438; 257/E23.134; 257/E29.158; 257/E29.16; 257/E29.161 |
| Class at Publication: |
438/197; 257/E21.266 |
| International Class: |
H01L 21/314 20060101 H01L021/314 |
Claims
1. A method of forming a gate structure comprising:forming at least one
gate region atop a semiconducting substrate, said at least one gate
region comprising a gate conductor atop a gate dielectric;forming source
and drain regions adjacent said at least one gate region;forming a
conformal dielectric passivation stack comprising a first conformal
dielectric layer and a second conformed dielectric layer on said at least
one gate region, wherein said conformal dielectric passivation stack
includes a discontinuous electrical path; andforming contacts to said
source and drain regions, wherein said contacts are electrically isolated
from said gate conductor by at least said conformal dielectric
passivation stack.
2. The method of claim 1 wherein said forming said conformal dielectric
passivation stack further comprises depositing at least one other
conformal dielectric layer atop said second conformal dielectric layer,
said at least one other conformal dielectric layer is seamless or having
at least one other seams offset from said at least one second seam.
3. The method of claim 1 wherein said first conformal dielectric layer and
said second conformal dielectric layer comprise an oxide, a nitride, or
an oxynitride.
4. The method of claim 1 wherein said first conformal dielectric layer and
said second conformal dielectric layer comprise the same material.
5. The method of claim 1 wherein said first conformal dielectric layer and
said second conformal dielectric layer comprise a different material.
6. The method of claim 1 wherein said first conformal dielectric layer is
deposited by plasma enhanced chemical vapor deposition (PECVD) and said
second conformal dielectric layer is deposited using a chemical vapor
deposition selected from the group consisting of atomic pressure chemical
vapor deposition (APCVD), low-pressure chemical vapor deposition (LPCVD),
rapid thermal chemical vapor deposition (RTCVD), plasma enhanced chemical
vapor deposition (PECVD), high density plasma chemical vapor deposition
(HDPCVD) and atomic layer deposition (ALD).
7. The method of claim 1 wherein said second conformal dielectric layer is
deposited by HPCVD.
8. The method of claim 1 her comprising forming a gate silicide atop said
gate conductor and a silicide contact region atop said source and drain
regions.
Description
RELATED APPLICATIONS
[0001]This application is a divisional application of U.S. Ser. No.
10/904,661, filed Nov. 22, 2004.
FIELD OF THE INVENTION
[0002]The present invention relates to semiconductor devices having
enhanced resistance to shorting, and more particularly to metal oxide
semiconductor field effect transistors (MOSFETS), in which electrical
shorting between the gate conductor and the contacts to the source and
drain regions of the device is substantially eliminated by a conformal
dielectric passivation stack positioned on at least the sidewalls of the
gate region. The inventive conformal dielectric passivation stack
comprises at least a first conformal dielectric layer and a second
conformal dielectric layer in which no electrical pathway is present that
extends entirely through the stack. The absence of the electrical pathway
can be achieved by using a second conformal dielectric that is seamless
or one in which the seams are offset from the seams present in the first
dielectric layer. The second dielectric layer thus covers any seams that
may be present in the first conformal dielectric layer.
BACKGROUND OF THE INVENTION
[0003]Field effect transistors (FETs) are the basic building block of
today's integrated circuits (ICs). Such transistors can be formed in
conventional substrates (such as silicon) or in silicon-on-insulator
(SOI) substrates.
[0004]State of the art MOS transistors are fabricated by depositing a gate
stack material over a gate dielectric and a substrate. Generally, the MOS
transistor fabrication process implements lithography and etching
processes to define the conductive, e.g., poly-Si, Si, gate structures.
Source/drain extensions are formed by implantation, in which the implant
is performed using a spacer to create a specific distance between the
gate and the implanted junction. In some instances, such as in the
manufacture of an NFET device, the source/drain extensions for the NFET
device are implanted with no spacer. For a PFET device, the source/drain
extensions are typically implanted with a spacer present. A thicker
spacer is typically formed after the source/drain extensions have been
implanted. Deep source/drain implants are then performed with the thick
spacer present. High temperature anneals are performed to activate the
junctions after which the source and drain regions and the top portion of
the gate are silicided. Silicide formation typically requires that a
refractory metal be deposited on the silicon wafer followed by a high
temperature thermal anneal process to produce the silicide material. The
structure is then passivated by a blanket deposited conformal dielectric
material.
[0005]In order to be able to make ICs, such as memory, logic, and other
devices, of higher integration density than currently feasible, one has
to find a way to further downscale the dimensions of field effect
transistors (FETs), such as metal oxide semiconductors. The downscaling
of transistor dimensions allows for improved performance as well as
compactness, but such downscaling has some device degrading effects.
[0006]Currently, the barrier passivation being used over MOSFET gate
regions is a nitride formed using a deposition process. Referring to FIG.
1, a conventional passivation layer 100 formed of a nitride conformally
deposited typically contains seams 101 through the deposited nitride
passivation layer 100. The seams 101 are typically present over changes
in topography of the deposited surfaces in which there is a change in
step height. The seams 101 which extend entirely through the nitride
passivation layer 100 provide an electrical path from the adjacent
contact 50 to the gate conductor 3, through the region 13 located beneath
the overlying gate silicide 12 and the gate conductor 3. This electrical
path can, in turn, result in device shorting. In FIG. 1, reference
numeral 2 is a gate dielectric, while reference numeral 4 is a spacer.
[0007]Further scaling of semiconducting devices requires that the
electrical pathways through the scams present in a conventional
passivation layer be interrupted to ensure that the electrical pathways
between the gate conductor and the contacts to the source and drain
region of the device be severed. Therefore, what is needed is a
passivation layer and a method of forming thereof which has discontinuous
electrical pathways.
SUMMARY OF THE INVENTION
[0008]An object of the present invention is to provide a field effect
transistor (FET) having a passivation stack comprising at least two
passivation layers in which a discontinuous electrical pathway through
the passivation stack is provided. In particular, this objective is
achieved in the present invention by providing a conformal dielectric
layered stack positioned on at least the sidewall portions of the gate
conductor, in which a first dielectric layer of the conformal dielectric
stack has seams which are covered by a second dielectric layer. The
second dielectric may contain seams or it may be seamless. When the
second dielectric is seamless, a discontinuous seam is provided in the
dielectric stack thereby preventing the formation of a complete
electrical pathway to the adjacent metal contact. It is noted that seams
are generally introduced into the first dielectric layer because of the
difference in step height within the structure.
[0009]When the second dielectric layer of the dielectric stack includes
seams, the seams of the second dielectric are offset from the seams
present in the first dielectric layer therefore providing a discontinuity
in the electrical pathway within the deposited layers caused by the seams
being aligned. By depositing multiple dielectric layers atop one another,
any seams present in the dielectric layers are covered or offset from one
another, therefore providing a conformal dielectric layered stack having
a discontinuous electrical pathway. In the present invention, the
passivation stack thus has discontinuous seams. The term "discontinuous
seams" denotes that the seams of each dielectric layer within the
conformal dielectric layered stack are covered or offset from one another
in a manner that would substantially eliminate electrical paths between
the gate conductor and contact of FET devices of current and future
generations of scaling.
[0010]Broadly, the inventive semiconducting device comprises:
a gate dielectric atop a semiconducting substrate, said semiconducting
substrate containing source and drain regions adjacent said gate
dielectric;a gate conductor atop said gate dielectric;a conformal
dielectric passivation stack positioned on at least said gate conductor
sidewalls, said conformal dielectric passivation stack containing a
discontinuous electrical pathway; anda contact to said source and drain
regions, wherein said conformal dielectric passivation stack
substantially eliminates shorting between said contact and said gate
conductor.
[0011]In accordance with the present invention, the conformal dielectric
passivation stack comprises a first conformal dielectric layer having at
least one first seam and a second conformal dielectric layer deposited
atop the first conformal dielectric layer, in which the second conformal
dielectric layer covers the first seams of the first conformal dielectric
layer. The second dielectric layer can be seamless or it can have seams
which are offset from the seams present in the first dielectric layer. In
one embodiment of the present invention, the conformal dielectric
passivation stack comprises a first conformal dielectric layer having at
least one first seam and a second conformal dielectric layer having at
least one second seam, wherein the at least one first seam is offset from
the at least one second seam to provide discontinuous seams, i.e.,
electrical pathways, through the conformal dielectric passivation stack.
The conformal dielectric passivation stack may further include at least
one other conformal dielectric layer that is seamless or having at least
one other seam positioned between the first conformal dielectric layer
and the second conformal dielectric layer, wherein the at least one other
seam is offset from any seams that may be present in the second
dielectric layer. Each of the dielectric layers in the conformal layered
dielectric stack can comprise the same or a different material, in which
the dielectric material may be a nitride, an oxide, or an oxynitride.
[0012]Another aspect of the present invention is a method of forming the
above-described semiconducting structure, which includes a conformal
dielectric passivation stack that does not include a continuous
electrical path therethrough, e.g., having discontinuous seams. Broadly,
the method of present invention comprises the steps of:
forming at least one gate region atop a semiconducting substrate, said at
least one gate region comprising a gate conductor atop a gate
dielectric;forming source and drain regions adjacent said at least one
gate region;forming a conformal dielectric passivation stack on said at
least one gate region, wherein said conformal dielectric passivation
stack includes a discontinuous electrical path; andforming contacts to
said source and drain regions, wherein said contacts are electrically
isolated from said gate conductor by at least said conformal dielectric
passivation stack.
BRIEF DESCRIPTION OF THE DRAWINGS
[0013]FIG. 1 is a pictorial representation (through a cross-sectional
view) showing a prior FET incorporating a single passivation layer
deposited atop a gate region in which seams in the passivation layer
provide a continuous electrical path through the passivation layer to the
gate conductor.
[0014]FIG. 2A is a pictorial representation (through a cross-sectional
view) of one embodiment of the inventive semiconducting structure in
which passivation of the gate conductor is provided by a conformal
layered dielectric stack wherein electrical isolation of the gate
conductor is provided by a discontinuity in seams between each dielectric
layer of the conformal layered dielectric stack, and FIG. 2B is a
pictorial representation (through a cross-sectional view) illustrating an
embodiment in which the second dielectric layer within the conformal
layered dielectric stack is seamless.
[0015]FIGS. 3-5 are pictorial representations (through cross-sectional
views) showing the basic processing steps that are employed to produce
the inventive semiconducting structure depicted in FIG. 2A.
DETAILED DESCRIPTION OF THE INVENTION
[0016]The present invention, which provides a method of passivating the
gate conductor of a field effect transistor with a conformal dielectric
passivation stack having discontinuous electrical pathways as well as the
structure that is formed from the inventive method, will now be described
in greater detail. It is noted that the drawings of the present
application are provided for illustrative purposes and thus they are not
drawn to scale. In particular, the dimensions of the seams and their
relative position to each other have been enlarged to exemplify the
present invention.
[0017]In the accompanying drawings, like and/or corresponding elements are
referred to by like reference numbers. In the drawings, a single gate
region is shown and described. Despite this illustration, the present
invention is not limited to a structure including a single gate region.
Instead, a plurality of such gate regions is contemplated.
[0018]Referring to FIG. 2A, in one embodiment of the present invention, a
field effect transistor (FET) is provided having a gate region 5 in which
the gate conductor 3 is passivated by a conformal dielectric passivation
stack 20. The gate region 5 also comprises a gate dielectric 2 underlying
the gate conductor 3 and a gate silicide 12 atop the gate conductor 3.
[0019]The conformal dielectric passivation stack 20 comprises a plurality
of dielectric layers 21, 22, 23 each having seams 51, 52, 53 offset from
one another. The offset seams 51, 52, 53 of the plurality of dielectric
layers 21, 22, 23 provide a conformal layered passivation stack 20 having
discontinuous seams, in which the discontinuous seams ensure that the
gate conductor 3 is electrically isolated from the contacts 50 to the
device. Although the plurality of dielectric layers 21, 22, 23 preferably
comprise Si.sub.3N.sub.4, the plurality of dielectric layers 21, 22, 23
may alternatively comprise an oxide, such as SiO.sub.2, Al.sub.2O.sub.3,
HfO, ZrO.sub.2, HfsiO, other dielectric materials that are common to
semiconductor processing or any combination thereof. Each of the
dielectric layers 21, 22, 23 of the conformal dielectric passivation
stack 20 may be the same or a different material.
[0020]The FET also comprises a semiconducting substrate 10 having source
and drain extension regions 7, deep source and drain regions 6, and
silicide contacts 11 located on a portion of the surface of the substrate
10 overlying the source and drain extension regions 7. A blanket
dielectric layer 55 is formed atop the FET 20. Vias in the blanket
dielectric layer 55 contain metal contacts 50 to the silicide contact 11
atop the source and drain regions.
[0021]One advantage of the inventive FET, as depicted in FIG. 2A, is that
the offset in the seams in each of the plurality of dielectric layers 21,
22, 23 of the conformal dielectric passivation stack 20 provides a
discontinuity in the seams through the conformal dielectric passivation
stack 20. The discontinuity in the seams through the conformal dielectric
passivation stack 20 ensures that the gate conductor 3 is electrically
isolated. In prior FETs, as illustrated in FIG. 1, continuous seams
through the passivation layer to the gate conductor provide an electrical
path to the gate conductor that could result in shorting of device
between the gate conductor 3 and the contacts 50 to the source and drain
regions 6,7. Referring back to FIG. 2A, the inventive conformal
dielectric passivation stack 20 comprising a plurality of dielectric
layers 21, 22, 23 each having seams 51, 52, 53 offset from one another
provide discontinuity between each of the seams, therefore ensuring
electrical isolation of the gate conductor 3.
[0022]FIG. 2B shows another embodiment of the present invention in which
the passivation stack 20 includes a first conformal dielectric 21 having
seams 51 and a second dielectric 22 which is seamless.
[0023]The method for forming the inventive FET shown in FIGS. 2A-2B are
now described in greater detail referring to FIGS. 3-5. It is noted that
drawing FIGS. 3-5 exemplify the embodiment shown in FIG. 2A. The
methodology described below, however, can also be used in forming the
structure shown in FIG. 2B except that the second dielectric film 22 of
the passivation stack 20 is seamless, Seamless films are formed utilizing
a high density plasma chemical vapor deposition process.
[0024]In accordance with the present invention, a gate region 5 is formed
atop a substrate 10 utilizing conventional methods including deposition
and lithography. Referring to FIG. 3, a gate stack is first provided atop
the substrate 10 by depositing a gate dielectric layer 2(a) and then a
gate conductor layer 3(a) using conventional deposition methods, such as
chemical vapor deposition.
[0025]The substrate 10 includes, but is not limited to: any semiconducting
material such as Si-containing materials, GaAs, InAs and other like
semiconductors. Si-containing materials include, but are not limited to:
Si, bulk, Si, single crystal Si, polycrystalline Si, SiGe, amorphous Si,
silicon-on-insulator substrates (SOI), SiGe-on-insulator (SGOI),
strained-silicon-on-insulator, annealed poly Si, and poly Si line
structures.
[0026]When the substrate 10 is a silicon-on-insulator (SOI) or
SiGe-on-insulator (SGOI) substrate, the thickness of the Si-containing
layer atop the buried insulating layer typically has a thickness on the
order of 10 nm or greater. The SOI or SGOI substrate may be fabricated
using techniques that are well known to those skilled in the art. For
example, the SOI or SGOI substrate may be fabricated using a thermal
bonding process, or alternatively by an ion implantation process, which
is referred to in the art as separation by ion implantation of oxygen
(SIMOX).
[0027]Still referring to FIG. 3, the gate dielectric layer 2(a), formed
atop the substrate 10, is typically an oxide material. The gate
dielectric layer 2(a) may also be composed of a nitride, oxynitride, or a
combination thereof. The gate dielectric layer 2(a) is formed using a
conventional technique such as chemical vapor deposition (CVD), atomic
layer CVD (ALCVD), pulsed CVD, plasma assisted CVD, sputtering, and
chemical solution deposition, or alternatively, the gate dielectric layer
2(a) is formed by a thermal growing process, which may include oxidation,
oxynitridation, nitridation, and/or plasma or radical treatment. Suitable
examples of oxides that can be employed as the gate dielectric layer 2(a)
include, but are not limited to: SiO.sub.2, A.sub.2O.sub.3, ZrO.sub.2,
HfO.sub.2, Ta.sub.2O.sub.3, TiO.sub.2, perovsklite-type oxides and
combinations and multi-layers thereof. The gate dielectric layer 2(a) is
subsequently etched to form the gate dielectric 2.
[0028]The gate conductor layer 3(a) is comprised of a conductive material
such as polysilicon or an appropriate metal. The gate conductor layer
3(a) is formed atop the gate dielectric layer 2(a) utilizing a
conventional deposition process such as CVD and sputtering. Preferably,
the gate conductor layer 3(a) comprises doped polysilicon. The
polysilicon dopant can be elements from Group III-A or an element from
Group V of the Periodic Table of Elements. The dopant may be introduced
during deposition of the gate conductor layer 3(a) after or following
subsequent patterning and etching of the gate conductor 3. Although the
gate conductor layer 3(a) preferably comprises doped polysilicon, the
gate conductor material may also be comprised of, metal silicides,
metallic nitrides, metals (for example, W, Ir, Re, Ru, Ti, Ta, Hf, Mo,
Nb, Ni, or Al) or other conductive materials.
[0029]Still referring to FIG. 3, a gate cap layer 8(a) is then optionally
formed atop the gate stack using deposition, p
hotolithography, and
etching. In one example, a gate cap layer 8(a) is first deposited atop
the gate stack and then patterned using photolithography and etching. The
gate cap layer 8(a) may comprise a dielectric that can be deposited by
chemical vapor deposition (CVD) and related methods. Typically, gate cap
layer 8(a) compositions include silicon oxides, silicon carbides, silicon
nitrides, silicon carbonitrides, etc. Spin-on dielectrics may also be
ulilized as the gate cap layer 8(a) including, but not limited to:
silsesquioxanes, siloxanes, and boron phosphate silicate glass (BPSG).
[0030]The gate cap layer 8(a) is then patterned using p
hotolithography.
Specifically, a pattern is produced by applying a photoresist to the
surface to be patterned, exposing the photoresist to a pattern of
radiation, and then developing the pattern into the photoresist utilizing
a conventional resist developer. Once the patterning of the p
hotoresist
is completed, the sections covered by the p
hotoresist are protected,
while the exposed regions are removed using a selective etching process
that removes the unprotected regions of the gate cap layer forming the
gate cap.
[0031]Referring to FIG. 4, following the formation of the gate cap, the
gate stack is then etched by a directional etch process, such as reactive
ion etching, having high selectivity for removing the material of the
gate conductor layer 3(a) and the gate dielectric layer 2(a) without
substantially etching the gate cap and the substrate 10. The resultant
gate region 5 includes a gate conductor 3 positioned atop a gate
dielectric 2. The gate cap 8(a) may then be removed using a chemical
strip or etch process.
[0032]In a preferred embodiment, following the formation of the gate
region 5, a thin sidewall spacer 4 is formed abutting and protecting the
sidewalls of the gate region 5. Preferably, the thin sidewall spacer 4 is
an oxide, such as SiO.sub.2. The thin sidewall spacer 4 has a width that
ranges from about 1 nm to about 20 nm, preferably being about 3 nm.
Forming processes such as deposition or thermal growing may produce the
thin sidewall spacer 4. Preferably, the thin sidewall spacer 4 is formed
by a deposition process such as chemical vapor deposition (CVD),
low-pressure chemical vapor deposition (LPCVD), rapid thermal chemical
vapor deposition (RTCVD), or plasma enhanced chemical vapor deposition
(PECVD) in combination with a directional reactive ion etch.
Alternatively, the thin sidewall spacer 4 may be formed using a low
temperature thermal oxidation of the gate region 5 in combination with a
directional reactive ion etch.
[0033]Source and drain extension regions 7 are then formed in substrate 10
and partially extend under the gate region 5. The source and drain
extension regions 7 are formed via ion implantation and comprise a
combination of normally incident and angled implants to form the desired
grading in the dopant regions. PFET devices are produced within
Si-containing substrates by doping the source and drain extension regions
7 with elements from Group V of the Periodic Table of Elements. NFET
devices are produced within Si-containing substrates by doping the source
and drain extension regions 7 with elements from Group III-A of the
Periodic Table of Elements. Halo regions can also be formed beneath the
source and drain extension regions 7 using an angled ion implantation and
a dopant having a conductivity type opposite the source and drain
extension regions 7.
[0034]Still referring to FIG. 4, following source and drain extension
region 7 implants, an offset spacer 14 may be formed abutting the
exterior surface of the thin sidewall spacer 4. In an alternative
embodiment, the offset spacer 14 may be formed abutting the gate
conductor 3 by omitting the thin sidewall spacer 4. The offset spacer 14
is formed using conventional deposition and etching, both of which are
well known in the art. The offset spacer 14 has a width that is greater
than the width of the thin sidewall spacer 4. The width of the offset
spacer 14 is dependent on the diffusivity of the dopant of the
subsequently formed deep source and drain regions 6 and typically ranges
from about 10 nm to about 60 nm. The offset spacer 14 can be comprised of
a dielectric material such as a nitride or a combination of oxide and
nitride materials, most preferably being Si.sub.3N.sub.4. It is noted
that although only one offset spacer 14 is depicted in FIG. 4, multiple
offset spacers have also been contemplated and are therefore within the
scope of the present invention. Alternatively, the offset spacer 14 may
be omitted.
[0035]Following offset spacer 14 formation, a higher energy ion implant is
conducted to form deep source and drain regions 6. These implants are
conducted at a higher energy and higher concentration of dopant than the
source and drain extension region 7 implant. The deep source and drain
regions 6 are typically doped with a dopant type consistent with the
source and drain extension regions 7.
[0036]Following deep source and drain region 6 formation, the source and
drain regions 6 and gate region 5 are activated by activation annealing
using a conventional process such as, but not limited to: rapid thermal
annealing, furnace annealing, flash lamp annealing or laser annealing.
Activation anneal is conducted at a temperature ranging from about
850.degree. C. to about 1350.degree. C.
[0037]Referring to FIG. 5, in a next process step, silicide regions 11, 12
are then formed atop the source and drain regions and the gate region 5.
Silicide formation typically requires depositing a metal layer onto the
surface of a Si-containing material or wafer. The metal layer may be
formed using a conventional process including, but not limited to:
chemical vapor deposition (CVD), plasma-assisted CVD, high-density
chemical vapor deposition (HDCVD), plating, sputtering, evaporation and
chemical solution deposition. Metals deposited for silicide formation
include Ta, Ti, W, Pt, Co, Ni, and combinations thereof, most preferably
being Co or Ni. Following deposition, the structure is subjected to an
annealing step using a conventional process such as, but not limited to:
rapid thermal annealing. During annealing, the deposited metal reacts
with Si forming a metal silicide. The gate silicide 12 formed atop the
gate conductor 2 typically results in the production of a void 13
positioned along the sidewall of the interface of the gate conductor 3
and the gate silicide 12.
[0038]Following silicidation, a conformal dielectric passivation stack 20
is formed atop the gate region 5 and the substrate 10. The conformal
dielectric passivation stack 20 comprises a plurality of dielectric
passivation layers 21, 22, 23, in which each passivation dielectric layer
has seams 51, 52, 53 that are offset from one another. The three layered
stack 20 described is provided for illustrative purposes only. It is also
possible in the present invention that the second dielectric passivation
layer or subsequent dielectrics are seamless.
[0039]The first conformal dielectric layer 21 is formed atop the gate
region 5 and the surface of the substrate 10 using a deposition or
thermal growth process and may comprise an oxide, nitride or oxynitride,
preferably being a nitride, such as Si.sub.3N.sub.4. The deposition
process may comprise chemical vapor deposition (CVD) including, but not
limited to: atomic pressure chemical vapor deposition (APCVD),
low-pressure chemical vapor deposition (LPCVD), rapid thermal chemical
vapor deposition (RTCVD), plasma enhanced chemical vapor deposition
(PECVD), high density plasma chemical vapor deposition (HDPCVD) or atomic
layer deposition (ALD). The thermal growth process may include thermal
oxidation, nitridation or oxynitridation. Combinations of the
aforementioned processes may also be used in forming the first conformal
dielectric layer 21. In a preferred embodiment, the first conformal
dielectric layer 21 is deposited using PECVD.
[0040]During deposition of the first conformal dielectric layer 21, seams
51 are typically formed extending from changes in topography in the
deposition surface through the deposited layer For example, as depicted
in FIG. 5, a first seam 51 may be formed extending from the region 13
positioned on the sidewall of the gate region 5 at the interface between
the gate silicide 12 and the gate conductor 3.
[0041]Still referring to FIG. 5, and in a next process step, a second
conformal dielectric layer 22 is deposited atop the first conformal
dielectric layer 21. The second dielectric layer 22 may comprise any
dielectric material and may be formed using any deposition process, so
long as the dielectric material of the second conformal dielectric layer
22 covers the first seams 51 in the first conformal dielectric layer 21.
The second dielectric layer 22 typically includes second seams 52 that
are offset from the first seams 51 of the first conformal dielectric
layer 21, as depicted in FIG. 5.
[0042]In one embodiment, the second dielectric layer 22 may comprise the
same dielectric material as the first dielectric layer 21 and may be
formed using the same forming process as the first dielectric layer 21,
so long as a break in the forming process of the first dielectric layer
21 and the second dielectric layer 22 is maintained. For example, the
first conformal dielectric layer 21 of Si.sub.3N.sub.4 can be deposited
and is followed by a break in deposition. Following the break in
deposition, deposition of Si.sub.3N.sub.4 resumes to provide the second
conformal dielectric layer 22 having second seams 52 that are offset from
the first seams 51 of the first conformal dielectric layer 21. In this
embodiment, the time period for the break in deposition must be
sufficient to provide that the seams 51, 52 of the first conformal
dielectric layer 21 and the second conformal dielectric layer 22 are
offset from one another to ensure that the scams through the conformal
dielectric passivation stack 20 are discontinuous.
[0043]In another embodiment of the present invention, the first conformal
dielectric layer 21 and the second conformal dielectric layer 22 may
comprise a different dielectric material. For example, since the first
dielectric layer 21 preferably comprises a nitride, such as
Si.sub.3N.sub.4, in this embodiment of the present invention, the second
conformal dielectric layer 22 comprises an oxide, such as SiO.sub.2, or
an oxynitride, such as SiO.sub.xN.sub.y. Alternatively, the second
conformal dielectric layer 22 may comprise a nitride when the first
conformal dielectric layer 21 comprises an oxide or oxynitride.
[0044]In yet another embodiment of the present invention, the first
conformal dielectric layer 21 and the second conformal dielectric layer
22 may be provided using different forming processes. For example, in a
preferred embodiment, the first conformal dielectric layer 21 may be
deposited using PECVD and the second conformal dielectric layer 22 may be
deposited using another deposition process selected from the group
consisting of, but not limited to: APCVD, LPCVD, RTCVD, PECVD, HDPCVD or
ALD. In another example, the second conformal dielectric layer 22 may be
formed using a thermal growth method such as thermal oxidation,
nitridation or oxynitridation.
[0045]The conformal layered stack 20 may further include one or more other
conformal dielectric layers 23. Although the conformal passivation stack
20 is depicted comprising three dielectric passivation layers 21, 22, 23,
any number of dielectric layer as is contemplated and is thus within the
scope of the invention, so long as the discontinuity of seams throughout
the conformal passivation stack 20 is maintained. When other dielectrics
are used, they may also be seamless.
[0046]Similar to the first conformal dielectric layer 21 and the second
conformal dielectric layer 22, the other conformal dielectric layer 23
may comprise a nitride, oxide, or oxynitride deposited using deposition
or thermal growth processes. The other conformal dielectric layer 23 may
comprise the same or a different material than the first and second
conformal dielectric layers 22, 23. The other conformal dielectric layer
may be formed using the same forming process or a different forming
process than the first and second conformal dielectric layers 22, 23. It
is noted that the other passivation layer 23 may be omitted, in which the
conformal dielectric passivation stack 20 consists of the first conformal
dielectric layer 21 and the second conformal dielectric layer 22. The
other passivation layer 23 may comprise a set of seams 53 that are offset
from at least the seams 52 within the second conformal dielectric layer
22. Also, the other passivation layer 23 may be seamless.
[0047]The offset seams 51, 52, 53 of the plurality of dielectric
passivation layers 21, 22, 23 provide a conformal dielectric passivation
stack 20 having discontinuous seams, in which the discontinuous seams
ensure that the gate conductor 3 is electrically isolated.
[0048]Following the formation of the conformal layered stack 20, an
interlayer dielectric 55 is blanket deposited atop the structure depicted
in FIG. 5 and planarized. The interlayer dielectric 55 may be selected
from the group consisting of silicon-containing materials such as
SiO.sub.2, Si.sub.3N.sub.4, SiO.sub.xN.sub.y, SiC, SiCO, SiCOH, and SiCH
compounds; the above-mentioned silicon-containing materials with some or
all of the Si replaced by Ge; carbon-doped oxides; inorganic oxides;
inorganic polymers; hybrid polymers; organic polymers such as polyamides
or SiLK.TM.; other carbon-containing materials; organo-inorganic
materials such as spin-on glasses and silsesquioxane-based materials; and
diamond-like carbon (DLC, also known as amorphous hydrogenated carbon,
a-C:H). Additional choices for the blanket dielectric include: any of the
aforementioned materials in porous form, or in a form that changes during
processing to or from being porous and/or permeable to being non-porous
and/or non-permeable.
[0049]The interlayer dielectric 55 may be formed by various methods well
known to those skilled in the art, including, but not limited to:
spinning from solution, spraying from solution, chemical vapor deposition
(CVD), plasma enhanced CVD (PECVD), sputter deposition, reactive sputter
deposition, ion-beam deposition, and evaporation.
[0050]The interlayer dielectric 55 is then patterned and etched using
conventional photolithography and etching to form vias to expose a
portion of the conformal dielectric passivation stack 20 overlying the
silicide contacts 11. The silicide contacts 11 are then exposed by an
etch chemistry that removes the exposed portions of the conformal
dielectric passivation stack 20, without etching the interlayer
dielectric 55 or the silicide contact 11. Metal contacts 50 to the
silicide contact 11 are then formed by depositing a conductive metal into
the via holes using conventional processing, such as sputtering or
plating. The conductive metal may include, but is not limited to:
tungsten, copper, aluminum, silver, gold, and alloys thereof.
[0051]While the present invention has been particularly shown and
described with respect to preferred embodiments thereof, it will be
understood by those skilled in the art that the foregoing and other
changes in forms and details may be made without departing from the
spirit and scope of the present invention. It is therefore intended that
the present invention not be limited to the exact forms and details
described and illustrated, but fall within the scope of the appended
claims.
* * * * *